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Linear response and stability of ordered phases of diblock copolymer melts

机译:二嵌段共聚物有序相的线性响应和稳定性   熔体

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摘要

An efficient pseudo-spectral numerical method is introduced for calculating aself-consistent field (SCF) approximation for the linear susceptibility ofordered phases in block copolymer melts (sometimes referred to as the randomphase approximation). Our method is significantly more efficient than that usedin the first calculations of this quantity by Shi, Laradji and coworkers,allowing for the study of more strongly segregated structures. We havere-examined the stability of several phases of diblock copolymer melts, andfind that some conclusions of Laradji et al. regarding the stability of theGyroid phase were the result of insufficient spatial resolution. We find thatan epitaxial (k=0) instability of the Gyroid phase with respect to thehexagonal phase that was considered previously by Matsen competes extremelyclosely with an instability that occurs at a nonzero crystal wavevector k.
机译:引入了一种有效的伪谱数值方法,用于计算嵌段共聚物熔体中有序相的线性磁化率的自洽场(SCF)近似(有时称为无规相近似)。我们的方法比Shi,Laradji及其同事在首次计算此数量时所使用的方法有效得多,从而可以研究更强烈隔离的结构。我们已经研究了二嵌段共聚物熔体几个相的稳定性,并发现Laradji等人的一些结论。关于Gyroid相的稳定性是空间分辨率不足的结果。我们发现,Matsen先前考虑的相对于六方相的Gyroid相的外延(k = 0)不稳定性与在非零晶体波矢k处出现的不稳定性极为接近。

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